In summary, we present a new versatile and practical Pdcatalyzed reaction for the synthesis of 4-vinyl-THBCs and 1-vinylTHGCs, via regioselective intramolecular AAA. The excellent levels in terms of yield and enantiomeric excess recorded suggest this strategy as a valuable candidate for the preparation of several classes of stereochemically defined polycyclic aromatic compounds.
Titolo: | Highly enantioselective synthesis of tetrahydro-beta-carbolines and tetrahydro-gamma-carbolines via Pd-catalyzed intramolecular allylic alkylation | |
Autori: | ||
Data di pubblicazione: | 2006 | |
Rivista: | ||
Abstract: | In summary, we present a new versatile and practical Pdcatalyzed reaction for the synthesis of 4-vinyl-THBCs and 1-vinylTHGCs, via regioselective intramolecular AAA. The excellent levels in terms of yield and enantiomeric excess recorded suggest this strategy as a valuable candidate for the preparation of several classes of stereochemically defined polycyclic aromatic compounds. | |
Handle: | http://hdl.handle.net/11562/736002 | |
Appare nelle tipologie: | 01.01 Articolo in Rivista |
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