Highly enantioselective synthesis of tetrahydro-beta-carbolines and tetrahydro-gamma-carbolines via Pd-catalyzed intramolecular allylic alkylation

Bandini, M.; Melloni, A.; Piccinelli, Fabio; Sinisi, R.; Tommasi, S.; Umani Ronchi, A.

doi:10.1021/ja054109o

In summary, we present a new versatile and practical Pdcatalyzed reaction for the synthesis of 4-vinyl-THBCs and 1-vinylTHGCs, via regioselective intramolecular AAA. The excellent levels in terms of yield and enantiomeric excess recorded suggest this strategy as a valuable candidate for the preparation of several classes of stereochemically defined polycyclic aromatic compounds.

Titolo:	Highly enantioselective synthesis of tetrahydro-beta-carbolines and tetrahydro-gamma-carbolines via Pd-catalyzed intramolecular allylic alkylation
Autori:	M. Bandini A. Melloni PICCINELLI, FABIO R. Sinisi S. Tommasi A. Umani Ronchi mostra contributor esterni nascondi contributor esterni
Data di pubblicazione:	2006
Rivista:	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Abstract:	In summary, we present a new versatile and practical Pdcatalyzed reaction for the synthesis of 4-vinyl-THBCs and 1-vinylTHGCs, via regioselective intramolecular AAA. The excellent levels in terms of yield and enantiomeric excess recorded suggest this strategy as a valuable candidate for the preparation of several classes of stereochemically defined polycyclic aromatic compounds.
Handle:	http://hdl.handle.net/11562/736002
Appare nelle tipologie:	01.01 Articolo in Rivista

File in questo prodotto:

Non ci sono file associati a questo prodotto.

Utilizza questo identificativo per citare o creare un link a questo documento:
http://hdl.handle.net/11562/736002

Citazioni

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

CATALOGO DEI PRODOTTI DELLA RICERCA

File in questo prodotto: