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EnglishThe double phosphate KLuP2O7 doped with Pr3+ ions was prepared by solid-state reaction. The material obtained was characterized by powder X-ray diffraction. The luminescence spectroscopy and the excited state dynamics of this material were studied upon excitation with VUV synchrotron radiation. The 5d-4f emission of Pr3+ upon both direct and band gap excitation was detected and assigned. The decay kinetics of the Pr3+ 5d-4f emission is characterized by a decay time of about 20 ns and is nearly temperature independent within the range 8-300 K. Both dynamics and energy transfer peculiarities revealed in the study suggested good potentials for application of KLuP2O7:Pr3+ as a fast scintillator material.
| Titolo: | Synchrotron Radiation Study of Interconfigurational 5d-4f Luminescence of Pr3+ in KLuP2O7 |
| Autori: | |
| Data di pubblicazione: | 2014 |
| Rivista: | |
| Abstract: | The double phosphate KLuP2O7 doped with Pr3+ ions was prepared by solid-state reaction. The material obtained was characterized by powder X-ray diffraction. The luminescence spectroscopy and the excited state dynamics of this material were studied upon excitation with VUV synchrotron radiation. The 5d-4f emission of Pr3+ upon both direct and band gap excitation was detected and assigned. The decay kinetics of the Pr3+ 5d-4f emission is characterized by a decay time of about 20 ns and is nearly temperature independent within the range 8-300 K. Both dynamics and energy transfer peculiarities revealed in the study suggested good potentials for application of KLuP2O7:Pr3+ as a fast scintillator material. |
| Handle: | http://hdl.handle.net/11562/728162 |
| Appare nelle tipologie: | 01.01 Articolo in Rivista |
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