New first examples of complexes with the general formula {[Ln(2)Sr(C4H3OCOO)(8)(H2O)(4)]}(n), where Ln = La3+ (1), Pr3+ (2), Nd3+ (3), Sm3+ (4), Eu3+ (5), Gd3+ (6), Tb3+ (7), Ho3+ (8), Yb3+ (9) and Er3+ (10) have been prepared and investigated by photoluminescence spectroscopy and magnetic susceptibility measurements. The X-ray crystal structure has been determined for the {[Er2Sr(C4H3OCOO)(8)- (H2O)(4)]}(n) (10) complex, indicating that this complex is built from two crystallographic independent coordination polymers {[Er2Sr(C4H3OCOO)(8)(H2O)(4)]}(n) in the triclinic crystal system and P-1 space group. The X-ray diffraction (XRD) pattern of the samples shows that all lanthanide compounds are isostructural to 10. The luminescence spectrum of a microcrystalline sample of "2Eu-Sr" compound displays the characteristic Eu3+ (D-5(0) -> F-7(J) (J = 0-4)) metal centred transitions; also "2Nd-Sr" proved to be luminescent in the near IR. Measurements of the magnetic susceptibility for 2, 3, 5 and 10 were described using Crystal Field approach

Synthesis, crystal structure, magnetic and luminescence investigations of new 2Ln3+-Sr2+ heteronuclear polymers with 2-furoic acid.

BETTINELLI, Marco Giovanni;SPEGHINI, Adolfo;
2007-01-01

Abstract

New first examples of complexes with the general formula {[Ln(2)Sr(C4H3OCOO)(8)(H2O)(4)]}(n), where Ln = La3+ (1), Pr3+ (2), Nd3+ (3), Sm3+ (4), Eu3+ (5), Gd3+ (6), Tb3+ (7), Ho3+ (8), Yb3+ (9) and Er3+ (10) have been prepared and investigated by photoluminescence spectroscopy and magnetic susceptibility measurements. The X-ray crystal structure has been determined for the {[Er2Sr(C4H3OCOO)(8)- (H2O)(4)]}(n) (10) complex, indicating that this complex is built from two crystallographic independent coordination polymers {[Er2Sr(C4H3OCOO)(8)(H2O)(4)]}(n) in the triclinic crystal system and P-1 space group. The X-ray diffraction (XRD) pattern of the samples shows that all lanthanide compounds are isostructural to 10. The luminescence spectrum of a microcrystalline sample of "2Eu-Sr" compound displays the characteristic Eu3+ (D-5(0) -> F-7(J) (J = 0-4)) metal centred transitions; also "2Nd-Sr" proved to be luminescent in the near IR. Measurements of the magnetic susceptibility for 2, 3, 5 and 10 were described using Crystal Field approach
lanthanide-strontium coordination polymer; furoic acid; luminescence spectra
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11562/302388
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