The Cu(I) coordination polymer [Cu-3(mu-I)(3)(mu-btz(Me))(NCCH3)](n) (btz(Me) = 1-methyl-1H-benzotriazole) was prepared and characterized by X-Ray diffraction. The compound showed strong green emission upon excitation with wavelengths below 475 nm, with lifetime of 47 mu s. The emission was attributed to (3)(X,M)LCT transition on the basis of experimental data and DFT calculations.

Luminescent copper(I) coordination polymer with 1-methyl-1H-benzotriazole, iodide and acetonitrile as ligands

Francesco Enrichi;
2019-01-01

Abstract

The Cu(I) coordination polymer [Cu-3(mu-I)(3)(mu-btz(Me))(NCCH3)](n) (btz(Me) = 1-methyl-1H-benzotriazole) was prepared and characterized by X-Ray diffraction. The compound showed strong green emission upon excitation with wavelengths below 475 nm, with lifetime of 47 mu s. The emission was attributed to (3)(X,M)LCT transition on the basis of experimental data and DFT calculations.
2019
Copper iodide
Coordination polymer
N-donor ligands
Luminescence
File in questo prodotto:
File Dimensione Formato  
105_2019_Bortoluzzi_InorgChemComm.pdf

solo utenti autorizzati

Descrizione: Articolo
Tipologia: Versione dell'editore
Licenza: Accesso ristretto
Dimensione 1.18 MB
Formato Adobe PDF
1.18 MB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11562/1064526
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 12
  • ???jsp.display-item.citation.isi??? 13
social impact