DNA hybrid catalysis goes organometallic: A DNA strand functionalized with diene ligands forms iridium(I) complexes that can efficiently catalyze an allylic amination in aqueous medium (see scheme). The DNA-based complexes show high stability and activity, and their secondary structure influences the stereoselectivity of the reaction.

Allylic Amination by a DNA-Diene-Iridium(I) Hybrid Catalyst

Fiammengo, R.;
2009-01-01

Abstract

DNA hybrid catalysis goes organometallic: A DNA strand functionalized with diene ligands forms iridium(I) complexes that can efficiently catalyze an allylic amination in aqueous medium (see scheme). The DNA-based complexes show high stability and activity, and their secondary structure influences the stereoselectivity of the reaction.
2009
allylic substitution
diene ligands
DNA
hybrid catalysis
iridium
Amination
Catalysis
DNA
Iridium
Kinetics
Oligonucleotides
Polyenes
Stereoisomerism
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11562/1025863
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