This chapter book gathers the finding on carbonyl clusters where the predominant metal in terms of atomic ratio belong to the either the 9th or the 10th group of the periodic table. In order to ensure a better focus, only compounds with a nuclearity of four metal atoms, and beyond, are included. The paragraphs are divided considering that metal carbonyl clusters can be either homo- and heterometallic, and that can be stabilized solely by carbonyl ligands but also in combination with other types of donor molecules. Furthermore, many carbonyl clusters of 9 and 10 group metals host main-groups elements, so separate paragraphs will be dedicated to carbide, nitride and phosphide compounds.
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