The synthesis, structural characterization, magnetic and catalytic properties of a new class of lanthanide-containing cationic heteropolyoxovanadium clusters with a nanochocolate-like structure are reported. The title compounds were characterized by single-crystal and powder X-ray diffraction, IR and V-51-NMR spectroscopies and magnetic susceptibility measurements.

Tetradecanuclear lanthanide-vanadium "nanochocolates": catalytically-active cationic heteropolyoxovanadium clusters

BETTINELLI, Marco Giovanni;SPEGHINI, Adolfo;
2013-01-01

Abstract

The synthesis, structural characterization, magnetic and catalytic properties of a new class of lanthanide-containing cationic heteropolyoxovanadium clusters with a nanochocolate-like structure are reported. The title compounds were characterized by single-crystal and powder X-ray diffraction, IR and V-51-NMR spectroscopies and magnetic susceptibility measurements.
2013
TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURES; POLYOXOVANADATES
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11562/642558
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