The synthesis, structural characterization, magnetic and catalytic properties of a new class of lanthanide-containing cationic heteropolyoxovanadium clusters with a nanochocolate-like structure are reported. The title compounds were characterized by single-crystal and powder X-ray diffraction, IR and V-51-NMR spectroscopies and magnetic susceptibility measurements.
Tetradecanuclear lanthanide-vanadium "nanochocolates": catalytically-active cationic heteropolyoxovanadium clusters
BETTINELLI, Marco Giovanni;SPEGHINI, Adolfo;
2013-01-01
Abstract
The synthesis, structural characterization, magnetic and catalytic properties of a new class of lanthanide-containing cationic heteropolyoxovanadium clusters with a nanochocolate-like structure are reported. The title compounds were characterized by single-crystal and powder X-ray diffraction, IR and V-51-NMR spectroscopies and magnetic susceptibility measurements.File in questo prodotto:
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