Reaction of [Re3(µ-H)4(CO)10]– with NOBF4 in CH2Cl2 gives the [{Re3(µ-H)3(CO)10}2(µ4-η2-NO)]– anion, containing a nitrosyl group which holds together two triangular cluster moieties by bridging one edge of each triangle through both the N and O atoms.
A novel Co-ordination mode of Nitric Oxide. Synthesis and Crystal Structure of the [{Re3(u-H)3(CO)10}2(u4-n2-NO)]- Anion
MOLINARI, Henriette;
1984-01-01
Abstract
Reaction of [Re3(µ-H)4(CO)10]– with NOBF4 in CH2Cl2 gives the [{Re3(µ-H)3(CO)10}2(µ4-η2-NO)]– anion, containing a nitrosyl group which holds together two triangular cluster moieties by bridging one edge of each triangle through both the N and O atoms.
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